Chemical Compatibility & Plastic Suitability

Don’t Let Chemicals Conquer Your Plastics: A Guide to Chemical Compatibility & Plastic Suitability

Ever poured the wrong cleaner into a container and witnessed the plastic warp or crack? It’s a frustrating (and sometimes hazardous) experience. But what if you could choose the perfect plastic for any chemical, ensuring its longevity and safety? At Valency Labs, we help you achieve just that.

 

Plastics are a cornerstone of modern life, but their interaction with chemicals varies greatly. Some plastics heroically withstand harsh environments, while others crumble under seemingly innocuous solutions. Understanding chemical resistance is crucial for selecting the right plastic for the job.

 

Imagine the peace of mind knowing your containers, pipes, or equipment can handle the chemicals they encounter daily. Valency Labs offers a comprehensive suite of services to ensure chemical compatibility for:

 

Membranes & GMFs (Gas Mixing Feeders): 

These play a vital role in various industries. Improper chemical selection can lead to leaks, reduced performance, and safety hazards. We provide a dedicated Chemical Compatibility Guide for Membranes & GMFs, tailored to your specific needs.

Valency Labs’ Chemical Compatibility Guide for Membranes & GMFs offers:

But wait, there’s more! We also delve into:

Incompatible Hazardous Chemicals: 

Certain chemicals pose a serious threat to specific plastics. Knowing these “red flags” can prevent catastrophic failures and safeguard your operations.

Partner with Valency Labs to unlock the secrets of plastic suitability!

Don’t let chemical compatibility remain a mystery.

Here’s how we can help:

Chemical resistance testing: 

We conduct rigorous testing to determine a plastic’s resistance to your specific chemicals.

Material selection guidance: 

Our experts recommend the most suitable plastic based on your application and chemical interactions.

Custom compatibility studies: 

For unique needs, we design and execute custom studies to ensure optimal results.

Contact Valency Labs today!

Let’s navigate the world of chemical compatibility together. With our expertise, you can choose plastics with confidence, ensuring their safety, performance, and longevity.

 


Chemical Resistance of Plastics

R Resistant
A Slowly attacked (not recommended for long term storage)
L Limited resistance
U Unsuitable

SW Swelling occurs
V Vapour diffusion
Environmental stress cracking

Chemical Polypropylene Polycarbonate Polyethylene
LD HD
  20°C 60°C 20°C 60°C 20°C 60°C 20°C 60°C
Acetic acid solution <90% R R R R R R R R
Acetic acid, glacial R U U U A U R L
Acetone R R U U E U R R
Ammonia R R U U R R R R
Aniline R R U U U U R R
Benzene A U U U U U U U
Boric Acid R R R R R R R R
Bromine U U U U U U U U
Carbon tetrachloride U U U U U U A U
Chlorinated Solvents U U U U U U U U
Chloroform U U U U U U U U
Cresols U U U U U U U U
Diethyl ether U U U U U U U U
Diethylene glycol R R R U R R R E
Ethers U U A U E U A U
Ethyl acetate A A U U A U A U
Ethanol R R R R R U R R
Ethylene glycol R R R U R R E E
Formaldehyde solution 40% R R R R R E R R
Formic acid R R R R R E R R
Hydrochloric acid cone. E E L U R R SW SW
Hydrofluoric acid 1-60% E E U U R R R L
Hydrofluoric acid cone. E E L u R U R L
Hydrogen peroxide 30-90% R R R R R U R A
Magnesium hydroxide R R R R R R R R
Maleic acid R R R R R R R R
Mineral oil R R R R A U R E
Nitric acid <25% R R R U R R R R
Nitric acid 25- 70% R E U U A U L U
Nitric acid >70 E U U u U U U U
Oxalic acid R A R R R R R R
Paraffin R A R R A U R R
Petroleum ether A U R R U U U U
Phosphoricacid<30% R R R R R R R R
Phosphoric acid 30-85% R R R R R A R R
Phosphoric acid >85% R R R R A U R A
Potassium hydroxide R R U U R R R R
Salicylic acid R R R R R R R R
Sodium hydroxide solution R R U U R R U U
Sulphuric acid <60% R R R R R R R R
Sulphuric acid 60-70% R U R R R A R A
Sulphuric acid>70% E U U U A U A L
Silicone oil R R R R A U E E
Stearic acid R R R R R R R R
“bluene U U U U U U U U
Trichloroethylene U U U U U U V U
Water R R R R R R R R



Chemical Compatibility Guide for Membranes & GMF

Compatible
      Limited Compatibility

 Not Compatible
     No Data Available

PTFE : Poly Tetra Fluoro Ethylene
PVDF : Polyvinylidene Fluoride
PES : Poly Ether Sulphone
PP : Poly Propylene
CA : Cellulose Acetate
RC : Regenerated Cellulose
CN : Cellulose Nitrate
GMF : Glass Microfibre Filter

ACIDS
  Nylon PTFE PVDF PES CA RC CN PP GMF
Acetic, Glacial  
Acetic, 25%
Hydrochloric, Concentrated
Hydrochloric, 25%  
Sulphuric, Concentrated
Sulphuric, 25%    
Nitric, Concentrated  
Nitric, 25%    
Phosphoric, 25%    
Formic, 25%  
Trichloroacetic, 25%  
ALKALIES
  Nylon PTFE PVDF PES CA RC CN PP GMF
Ammonium Hydroxide, 25%    
Sodium Hydroxide, 25%  
ALCOHOLS
  Nylon PTFE PVDF PES CA RC CN PP GMF
Methanol, 98%
Ethanol, 98%  
Ethanol, 70%    
Isopropanol  
n-Propanol
Amyl Alcohol, Butanol
Benzyl Alcohol      
Ethylene Glycol  
Propylene Glycol  
Glycerol
HYDROCARBONS
  Nylon PTFE PVDF PES CA RC CN PP GMF
HYDROCARBONS                  
Hexane, Xylene
Toluene, Benzene
Kerosene, Gasoline  
Tetralin, Decalin
HALOGENATED HYDROCARBONS
  Nylon PTFE PVDF PES CA RC CN PP GMF
Methylene Chloride    
Chloroform
Trichloroethylene  
Monochlorobenzene    
Freon  
Carbon Tetrachloride    
KETONES
  Nylon PTFE PVDF PES CA RC CN PP GMF
Acetone
Cyclohexanone
Methyl Ethyl Ketone    
Isopropylacetone
Methyl Isobutyl Ketone  
ESTERS
  Nylon PTFE PVDF PES CA RC CN PP GMF
Ethyl & Methyl Acetate
Amyl & Butyl Acetate  
Propyl Acetate  
Propylene Glycol Acetate
2-Ethoxyethyl Acetate  
Methyl Cellosolve Acetate
Benzyl Benzoate
Isopropyl Myristate
Tricresyl Phosphate
OXIDES – ETHERS
  Nylon PTFE PVDF PES CA RC CN PP GMF
Ethyl Ether
Dioxane
Tetrahydrofuran
Triethanolamine
Dimethylsulfoxide (DMSO)
Isopropyl Ether
SOLVENTS WITH NITROGEN
  Nylon PTFE PVDF PES CA RC CN PP GMF
Dimethyl Formamide
Diethylacetamide
Triethanolamine
Aniline
Pyridine
Acetonitrile
MISCELLANEOUS
  Nylon PTFE PVDF PES CA RC CN PP GMF
Phenol, Aqueous, 10%
Formaldehyde Solution, 30%
Hydrogen Peroxide, 30%
Silicone Oil & Mineral Oil



Incompatible Hazardous Chemicals

Chemicals in the left hand column should be stored under controlled conditions and these chemicals should not come in contact with the right hand column otherwise, a reaction will be violent and lead to an accident.
Acetic acid Chromic acid, nitric acid, peroxides and permanganates
Acetic anhydride Hydroxyl-containing compounds, ethylene glycol, perchloric acid
Acetone Concentrated nitric and sulphuric acid mixtures, hydrogen peroxide
Acetylene Chlorine, bromide, copper, silver, fluorine and mercury
Alkali and alkaline earth metals such as sodium, potassium, lithium, magnesium, calcium Carbon dioxide, carbon tetrachloride and other chlorinated hydrocarbons. (Also prohibit water, foam and dry chemicals onfires involving these metals -dry sand should be available)
Aluminium powder Halogenated or oxygenated solvents
Ammonia, anhydrous Mercury, chlorine, calcium hypochlorite, iodine, bromine and hydrogen fluoride
Ammonium nitrate Acids, metal powders, flammable liquids, chlorates, nitrates, sulphur, finely divided organics or combustibles
Aniline Nitric acid, hydrogen peroxide
Bromine Ammonia, acetylene, butadiene, butane and other petroleum gases, sodium carbide, turpentine, benzene and finely divided metals
Calcium oxide Water
Carbon, activated Calcium hypochlorite
Chlorates Ammonium salts, acids, metal powders, phosphorus, sulphur, finely divided orqanics or combustibles
Chromic acid and chromium trioxide Acetic acid, naphthalene, camphor, phosphorus, sulphur, finelydivided organics or combustibles
Chlorine Ammonia, acetylene, butadiene, butane, other petroleum gases, hydrogen, sodium carbide, turpentine, benzene and finely divided metals
Chlorine dioxide Ammonia, methane, phosphine and hydrogen sulphide
Copper Acetylene, hydrogen peroxide
Fluorine Isolate from everything
Hydrazine Hydrogen peroxide, nitric acid, any other oxidant and heavy metal salts
Hydrocarbons (benzene, butane, propane, gasoline, turpentine etc) Fluorine,chlorine, bromine, chromic acid, cone. Nitric acid, peroxides
Hydrogen cyanide Nitric acid, alkalis
Hydrogen fluoride Ammonia, aqueous or anhydrous
Hydrogen peroxide Copper, chromium, iron, most metals or their salts, any flammable liquid, combustible materials, aniline, nitromethane
Hydrogen sulphide Fuming nitric acid, oxidising gases
Iodine Acetylene, ammonia (anhydrous or aqueous)
Mercury Acetylene, fulminic acid*, ammonia
Nitric acid (cone.) Acetic acid, acetone, alcohol, aniline, chromic acid,hydrogen cyanide, hydrogen sulphide, flammable liquids, flammable gases, nitratable substances, fats, grease
Nitromethane, lower nitroalkanes Inorganic bases, amines, halogens, 13X molecular sieve
Oxalic acid Silver, mercury, urea
Oxygen Oils, grease, hydrogen, flammable liquids, solids or gases
Perchloric acid Acetic anhydride, bismuth and its alloys, alcohol, paper, wood, grease, oils, dehydrating agents
Peroxides, organic Acids (organic or mineral), avoid friction, store cold
Phosphinates Any oxidant
Phosphorus (white) Air, oxygen
Potassium chlorate Acids (see also chlorates)
Potassium perchlorate Acids (see also perchloric acid)
Potassium permanganate Glycerol, ethylene glycol, benzaldehyde, sulphuric acid
Silver Acetylene, oxalic acid, tartaric acid, fulminic acid*, ammonium compounds
Sodium See alkali metals (above)
Sodium nitrate Ammonium nitrate and other ammonium salts
Sodium peroxide Any oxidizable substance, such as ethanol, methanol, glacial acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerol, ethylene glycol, ethyl acetate, methyl acetate, furfural
Sulfuric Sulphuric acid Chlorates, perchlorates, permanganates
Thiocyanates Metal nitrates, nitrites, oxidants
Trifluoromethane sulfonic acid Perchlorate salts
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